Material Safety Data Sheet

1. IDENTIFICATION OF SUBSTANCE/PREPARATION AND COMPANY

Commercial Product Name

Nonyl Phenol Ethoxylate-8

Uses

detergents;  cleaning  agent  (products  for  professional  use);  pesticides; auxiliary tanning agents; Chemical processes general

Manufacture

Ningbo Lucky Chemical Co., Ltd

Emergency Number

8,657,487,849,999

2. COMPOSITION/INFORMATION ON INGREDIENTS

Composition

CAS NO.

Content

Nonyl Phenol Ethoxylated

9016-45-9

≥98%

Polyethylene Glycol

25322-68-3

≥1.5%

Water

7732-18-5

≤0.5%

3. HAZARDS IDENTIFICATION

Classification

Xi; R36/38

Irritating to eyes and skin.

N; R51/53

Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.

Hazard symbols

Xi

Irritant

N

Dangerous for the environment

R phrases

36/38

Irritating to eyes and skin.

51/53

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Warming Label

4. FIRST-AID MEASURES

General information

Poisonous symptoms can first be observed after several hours,

therefore medical observation for at least 48 hours is necessary. If the patient is likely to become unconscious, place and transport in stable sideways position. Remove contaminated clothing

immediately and dispose of safel.

After inhalation

Remove affected person from the immediate area. Ensure supply of fresh air. In case of persisting adverse effects consult a physician.

After skin contact

in case of contact with skin wash off immediately with soap and water. Consult a doctor if skin irritation persists.

After eye contact

In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water. Eye treatment by an oculist.

After ingestion

Do not induce vomiting. Rinse out mouth and give plenty of water to drink. Summon a doctor immediately.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

Water; Alcohol-resistant foam; extinguishing powder; Carbon dioxide; Sand

Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases

Fire gas of organic material has to be classed invariably as respiratory poison. In the event of fire, the following can be released: Carbon dioxide(CO2), Carbon monoxide (CO)

Special Protective Equipment for
Firefighters

Fire-fighting operations, rescue and clearing work under effect of combustion and smoulder gases just may be done with breathing apparatus.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions

High risk of slipping due to leakage/spillage of product. Refer to protective measures listed in sections 7 and 8.

Environmental Precautions

Do not discharge into the drains/surface waters/groundwater. Do not discharge into the subsoil/soil.

Methods for Cleaning Up

Pick up with absorbent material. When picked up, treat material as prescribed under heading "Disposal considerations".

7. HANDLING AND STORAGE

Handling

Advice on safe handling
No special measures necessary if stored and handled as prescribed. Provide good ventilation of working area (local exhaust ventilation if necessary).
Advice on protection against fire and explosion
Avoid effect of heat.
Classification of fires
B

Storage

Requirements for storage rooms and vessels
Containers which are opened must be carefully resealed and kept upright to prevent leakage. Prevent penetration into the ground.
Further information on storage conditions
Protect from heat and direct sunlight. Protect from contamination. Keep container tightly closed in a cool, well-ventilated place, open and handle carefully.

Packaging Type

Original packaging offered by manufacturer

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Personal Protective Equipment

The usual precautionary measures for handing chemicals should be followed.

Respiratory Protection

Breathing apparatus in the event of aerosol or mist formation.

Hand protection

In  case  of  intensive  contact wear protective  gloves  (EN  374). Sufficient protection is given wearing  suitable protective gloves checked according  to  i.e.  EN  374,  in  the  event  of  risk  of  skin contact with the product . Before use, the protective glove should be tested in any case for its specific work-station suitability (i.e. mechanical resistance, product compatibility and antistatic properties). Adhere to the manufacturer’s  instructions and information relating to the use, storage, care and replacement of protective gloves. Protective gloves shall be replaced
immediately when physically damaged or worn. Design operations thus to avoid permanent use of protective gloves.

Eye Protection

Safety glasses with side protection shield (EN 166)

Skin protection

Light protective clothing

General protective and hygiene measures

Do  not  eat  or  drink  during  work  time.  Provide  washing facilities  at the  place  of  work.  Remove  soiled  or  soaked clothing  immediately. Keep  separated  from  food-stuffs  and feed-stocks.  Use  barrier  skin cream.  Wash  hands  before breaks and after work. Avoid contact with eyes and skin.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance (25℃)

Colourless to yellow liquid

Odor

Characteristic odor

Solubility in water

soluble

pH-value (1% aqueous solution)

5.0-7.0

Density(g/cm³, 20℃)

1.04

Viscosity(mm²/s,20℃)

approx. 400

OHV(mg KOH/g)

93-103

CHROMA( Pt-Co,50     ℃)

≤50

Flash Point (℃)

197

10. STABILITY AND REACTIVITY

Stability

Stable under normal conditions of use and storage according to instructions.

Conditions to Avoid

If accurately spreading out possibility of self-inflammation.

Thermal decomposition

No decomposition if used as prescribed

Hazardous Decomposition Products

No  hazardous  decomposition  products  if  well  stored  and handled.

11. TOXICOLOGICAL INFORMATION

Acute toxicity

Acute oral toxicity

Remarks

No data available.

Acute dermal toxicity

Remarks

No data available.

Acute inhalational toxicity

Remarks

No data available.

Irritant/corrosive effects

Irritant effect on skin

Evaluation

irritant

Irritant effect on eyes

Evaluation

irritant

Sensitisation

Remarks

No data available.

Effects after repeated or prolonged exposition (subacute, subchronic, chronic)

Mutagenicity

Remarks

No data available.

Reproduction toxicity

Remarks

No data available.

Carcinogenicity

Remarks

No data available.

Experience in practice

Irritates the mucous membrane.

12. ECOLOGICAL INFORMATION

Ecotoxicity

EC50

14mg/l

Species

Crustacean

Duration of exposure

48h

ErC50

12mg/l

Species

Algae

Duration of exposure

96h

LC50

6mg/l

Species

Fish

Duration of exposure

96h

Other adverse effects

Do not allow to enter soil, waterways or waste water canal.

13. DISPOSAL CONSIDERATIONS

Product

Allocation  of  a  waste  code  number,  according  to  the  European  Waste Catalogue, should be carried out in agreement with the regional waste disposal company.

Packaging

Residuals must be removed from packaging and when emptied completely disposed of
in accordance with the regulations for waste removal. Incompletely emptied packaging must be disposed of in the form of disposal specified by the regional disposer.

14. TRANSPORT INFORMATION

Land transport ADR/RID
Class

9                                                  Classification code         M6                  

Packaging group

III

Hazard id. no.

90

Label

9

UN number

3082

Technical name

Environmentally hazardous substance, liquid, n.o.s.

Danger releasing substance

Nonylphenol Ethoxylate 6 mol

Marine transport IMDG
Class

9

Packaging group

III

UN number

3082

Proper shipping name

Environmentally hazardous substance, liquid, n.o.s.

Danger releasing substance

Nonylphenol Ethoxylate 6 mol

EmS

F-A, S-F

MARPOL

-

Label

9

Air transport ICAO/IATA
Class

9

Packaging group

III

UN number

3082

Proper shipping name

Environmentally hazardous substance, liquid, n.o.s.

Danger releasing substance

Nonylphenol Ethoxylate 6 mol

Label

9

15. REGULATORY INFORMATION

Labelling in accordance with EC directives

The product is classified and labelled in accordance with EC directives/ GefStoffV  (German  regulations  on  dangerous  substances).Nonylphenol Ethoxylate 8 mol

Hazard Symbol(s)

Xi:Irritant
N: Dangerous for the environment

R-phrase(s)

R36/38: Irritating to eyes and skin.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

S-phrase(s)

S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S61: Avoid release to the environment. Refer to special instructions/ Safety data sheets.

16. OTHER INFORMATION

Further information

The information is based on our current knowledge however it does not represent a guarantee of product properties nor does it create any legal obligation.

Sources of key data used to compile the data sheet:

National Threshold Limit Values of the corresponding countries as amended  in  each  case.  Transport  regulations  according  to  ADR, RID, IMDG, IATA as amended in each case.